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PROPERTIES OF IP-TiN COATINGS MODIFIED BY AI AND La

JIN Zhujing YU Li DAI Shaoxia YU Zhiming Institute of Corrosion and Protection of Metals , Academia Sinica , Shenyang , China YU Li Research Assistant , Institute of Corrosion and Protection of Metals , Academia Sinica.Shenyang 110015 , China

金属学报(英文版)

A modified ion-plated TiN(IP-TiN) coating has been developed by adding 6 wt-% A1 and small amounts of La.Examination of this coating showed that the adhesion between the coat- ing and substrate is remarkably improved by the La added up to 2 wt-% ,and the microhardness and wear resistance of the coating surface closely relate to the contents of La.EPMA and X-ray diffraction analysis indicated that a thick transition zone forms owing to the addition of La and A1.The phase composition and grain orientation of the coating change because of the formation of such transition zone.Thus,the properties of coating were improved.

关键词: ion plated TiN coating , null , null , null

添加元素Al,La改性IP-TiN膜性能研究

金柱京 , 于力 , 戴少侠 , 于志明

金属学报

本文在离子镀TiN(IP-TiN)膜的基础上添加了6wt-%的金属元素Al和不同微量的稀土元素La(0.1,1.0,2.0wt-%),获得了改性的IP-TiN膜(称Al,La改性IP-TiN)。通过对镀膜性能的检测发现,当La含量增加到2wt-%时,镀膜与基材的附着强度明显提高;镀膜表面显微硬度、耐磨性亦随La含量增高出现有规律变化。经电子探针及X射线衍射分析认为是添加元素在镀膜与基材界面上形成较宽的使镀膜相组成及晶粒取向改变的过渡带所致。

关键词: 离子镀氮化钛 , Al , La , adhesivity

稀土元素钇改善离子镀TiN膜与基材结合力的研究

金柱京 , 于力 , 戴少侠 , 于志明

金属学报

本文叙述了添加稀土元素Y改善了离子镀TiN膜与基材的结合力,并且通过电子探针(EPMA)、透射电镜(TEM)和X射线衍射相分析等手段,对稀土元素Y在离子镀TiN(IP-TiN)膜中的行为和存在形态进行了分析,进一步探讨了稀土元素Y改善IP-TiN膜与基材结合力的机制,从而肯定了稀土元素Y提高IP-TiN膜与基材结合力的作用。

关键词: 离子镀TiN涂层 , adhesion , Y

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